On Saturday she drove Romania's world number one Simona Halep to distraction at Wimbledon, using her Pandora's box of drop shots, lobs, slices and wristy winners to claim a memorable 3-6 6-4 7-5 win on a mesmerised Court One to reach the last 16.
Over on Court One, fourth seed Alexander Zverev made another shocking exit as Latvian Ernests Gulbis conquered the German world No. 3 in five sets 7-6 (7-2), 4-6, 5-7, 6-3, 6-0.
Chinese-Taipei 's Hsieh Su-Wei will next face Dominika Cibulkova of Slovakia in the round of 16. Japan's Kei Nishikori celebrates winning his third round match against Australia's Nick Kyrgios.
'I will not find the excuses about this match, she deserved to win, but still, I'm sad about myself today, ' Halep said.
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Lovren, whose nation are into the semi-finals for the first time since 1998, said Croatia could play with freedom. They have not advanced to the Final since 1966, when they won it all.
"I knew what to expect, we played a lot of tough battles in the past", Kerber said of Osaka.
Latvia's 12th seed Jelena Ostapenko needed just 62 minutes to put away Russia's Vitalia Diatchenko in a 6-0 6-4 victory. "I just try to run as much as I can, try to catch every ball".
"I mean, I'm not surprised anymore", said 2017 French Open champion Ostapenko, a 6-0, 6-4 victor against Vitalia Diatchenko, who eliminated five-time major champion Maria Sharapova in the first round.
Asked when she thought she could win the match, Hsieh responded, "I don't feel I can", then leaned forward and laughed heartily. If I give it my all, I'm happy.
Third seed Muguruza joined second seed Caroline Wozniacki, fourth seed Sloane Stephens, fifth seed Elina Svitolina, sixth seed Caroline Garcia and eighth seed Petra Kvitova on the way out, along with five-time Grand Slam champion Maria Sharapova.
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Hsieh, who has never reached the last 16 at Wimbledon, stepped up her game in the second set as she broke twice to level the match.
Making her fourth appearance at Wimbledon, Ostapenko will look to improve on her run to the quarter-finals past year. By the time she played her third-round match at the All England Club, she was being watched with the type of concern normally reserved for endangered species.
Next up for is Van Uytvanck will be 14th seed Daria Kasatkina, the Russian beating 17th-seeded Australian Ashleigh Barty 7-5 6-3 on Court Three.
Then there is Stephens, the US Open champion of a year ago who struggled for form immediately after winning her home Slam, losing in the first round of the next four tournaments (including the Australian Open).
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